Henrik Stenson was stripped of Team Europe's Ryder Cup captaincy on Wednesday, a few hours before the Swede announced that he was joining the lucrative Saudi-backed LIV Golf Invitational Series.
The 2016 British Open champion helped Europe to victory in three of his five Ryder Cup appearances as a player, including the last home tournament at Le Golf National in 2018.
Stenson, 46, was also vice-captain to Padraig Harrington at Whistling Straits last year and had been tasked with regaining the trophy following Europe's record 19-9 defeat to the United States team in Wisconsin.
Ryder Cup Europe said in a statement that "in light of decisions made by Henrik in relation to his personal circumstances, it has become clear he will not be able to fulfil certain contractual obligations and it is therefore not possible for him to continue in the role of captain.
"Confirmation of the new 2023 European Ryder Cup Captain will be made in due course."
Stenson later confirmed on Twitter that he would play in the third LIV Golf tournament of the season from July 29-31 in New Jersey at Trump National Golf Club Bedminster.
"My interest in this concept has been well documented over the past few years," Stenson said.
Bankrolled by Saudi Arabia's Public Investment Fund, LIV Golf held its first event in London last month which was won by South Africa's Charl Schwartzel, who pocketed the $4 million prize – the biggest pay cheque in golf history.
Critics of the new series say it amounts to 'sportswashing' by a nation trying to improve its reputation in light of its history of human rights abuses.
The Marco Simone Golf & Country Club in Rome, Italy hosts the next edition of the biennial Ryder Cup starting in late September next year.